Photocatalytic Multicomponent Carboxylation of Olefins and Sulfinate Salts with <sup>13</sup>CO<sub>2</sub>
Herein, we describe a photoinduced multicomponent catalytic carboxylation protocol that streamlines the access to 13C-labeled carboxylic acids from simple olefin precursors, sulfinate salts and 13CO2. Site selectivity is dictated by the radical philicity of the starting precursors and reaction intermediates, resulting in either a four-component or a five-component endeavor. The method is characterized by its simplicity and flexibility across a wide number of coupling counterparts
Authors
- Rubén Martı́n (ORCID: https://orcid.org/0000-0002-2543-0221)
- Márcio W. Paixão (ORCID: https://orcid.org/0000-0002-0421-2831)
- Julien R. Lyonnet (ORCID: https://orcid.org/0000-0001-7466-5011)
- José Tiago Menezes Correia (ORCID: https://orcid.org/0000-0002-4410-7788)
- Roman Abrams (ORCID: https://orcid.org/0000-0001-7357-7298)
- Álvaro Velasco‐Rubio (ORCID: https://orcid.org/0000-0003-1477-4747)
- Charles S. Elmore (ORCID: https://orcid.org/0000-0001-7434-8307)
- Alessandro Cerveri
- Ha Phan (ORCID: https://orcid.org/0000-0002-2041-9218)
- Kim S. Mühlfenzl (ORCID: https://orcid.org/0000-0003-3700-0891)
- Xuemeng Chen (ORCID: https://orcid.org/0000-0003-3024-7488)
Institutions
- Institució Catalana de Recerca i Estudis Avançats (ES)
- Stockholm University (SE)
- Universidade Federal de São Carlos (BR)
- Universidade de São Paulo (BR)
- Instituto Butantan (BR)
- Institut Català d'Investigació Química (ES)
- AstraZeneca (Sweden) (SE)
- Universitat Rovira i Virgili (ES)
- Technical University of Denmark (DK)
Publication Details
- Journal
- ACS Catalysis
- Published
- 2024-12-06
- DOI
- https://doi.org/10.1021/acscatal.4c06335
- Citations
- 6
- Primary Topic
- Carbon dioxide utilization in catalysis
- Type
- article
- Field-Weighted Citation Impact
- 1.07
Funders
- Ministerio de Ciencia, Innovación y Universidades
- Fundação de Amparo à Pesquisa do Estado de São Paulo
- Institut Català d'Investigació Química
- Ministerio de Ciencia e Innovación
- European Regional Development Fund
- H2020 Marie Skłodowska-Curie Actions