Cyaphide group transfer from covalent metal complexes: contrasting pathways to transmetallation
We describe two contrasting transmetallation reactions between the gold(I) cyaphide complex, Au(IDipp)(CP) (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene), and low oxidation state main-group and transition-metal complexes. The reactivity observed highlights the pseudo-halide character of the cyaphide ion.
Authors
- José M. Goicoechea (ORCID: https://orcid.org/0000-0002-7311-1663)
- Eric S. Yang (ORCID: https://orcid.org/0000-0002-0851-655X)
Institutions
- University of Oxford (GB)
- Indiana University Bloomington (US)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-06
- DOI
- https://doi.org/10.1039/d4cc06131d
- Primary Topic
- Synthesis and characterization of novel inorganic/organometallic compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00