Selective electroreduction of CO <sub>2</sub> to formate by a heterogenized Ir complex using H <sub>2</sub> O as an electron/hydrogen source
A new PNNP-coordinated iridium complex, Mes-IrPPh2, immobilized on carbon was a superior catalyst for the CO 2 electrochemical reduction in water to give formate, allowing the solar-to-chemical conversion efficiency of 13.7%.
Authors
- Naonari Sakamoto (ORCID: https://orcid.org/0000-0002-6159-4792)
- Keita Sekizawa (ORCID: https://orcid.org/0000-0003-2660-0410)
- Shunsuke Sato (ORCID: https://orcid.org/0000-0001-8178-7367)
- Keun‐Woo Lee (ORCID: https://orcid.org/0000-0002-3153-190X)
- Jieun Jung (ORCID: https://orcid.org/0000-0002-5310-8643)
- Susumu Saito (ORCID: https://orcid.org/0000-0003-0749-2020)
- Tomiko M. Suzuki (ORCID: https://orcid.org/0000-0003-3763-4245)
- Takeshi Morikawa (ORCID: https://orcid.org/0000-0002-4985-0925)
- Kenji Kamada (ORCID: https://orcid.org/0000-0002-2532-5448)
- Taku Wakabayashi (ORCID: https://orcid.org/0000-0002-2083-3590)
- K. Selvam (ORCID: https://orcid.org/0000-0001-7539-871X)
Institutions
- Toyota Central Research and Development Laboratories (Japan) (JP)
- Nagoya University (JP)
Publication Details
- Journal
- EES Catalysis
- Published
- 2024-12-06
- DOI
- https://doi.org/10.1039/d4ey00261j
- Citations
- 4
- Primary Topic
- CO2 Reduction Techniques and Catalysts
- Type
- article
- Field-Weighted Citation Impact
- 0.41
Funders
- Ministry of Education, Culture, Sports, Science and Technology
- Japan Society for the Promotion of Science
- Core Research for Evolutional Science and Technology