Reversing selectivity of bambusuril macrocycles toward inorganic anions by installing spacious substituents on their portals
Two chiral bambusurils, which are diastereomers to each other, show remarkable differences in their binding affinity and selectivity toward inorganic anions as determined by isothermal titration calorimetry. These differences are explained by quantum-chemical calculations.
Authors
- Carola Rando (ORCID: https://orcid.org/0000-0002-9756-5600)
- Vladimír Šindelář (ORCID: https://orcid.org/0000-0003-0090-5961)
- Petr Kulhánek (ORCID: https://orcid.org/0000-0002-4152-6514)
- Jan Sokolov
- Surbhi Grewal (ORCID: https://orcid.org/0000-0002-8314-5381)
Institutions
- Masaryk University (CZ)
Publication Details
- Journal
- Chemical Science
- Published
- 2024-12-06
- DOI
- https://doi.org/10.1039/d4sc07150f
- Citations
- 3
- Primary Topic
- Nanomaterials for catalytic reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.75
Funders
- European Commission
- Ministerstvo Školství, Mládeže a Tělovýchovy
- Grantová Agentura České Republiky
- Horizon 2020 Framework Programme
- RECETOX Přírodovědecké Fakulty Masarykovy Univerzity