Integrated Carbon Nanotube and Ketoenamine‐Linked Covalent Organic Framework with Positive Charge Structure as High‐Performance Capacitive Materials

A series of composite materials, ETB@CNT (ETB@CNT10, ETB@CNT20, ETB@CNT30, ETB@CNT40, ETB@CNT50) with different carbon nanotubes (CNTs) contents are successfully prepared by using one-pot method. Compared with the pure ET-B-COF, which is a ketoenamine-linked covalent organic framework (COF) with a positive charge structure, CNTs can effectively improve the electrochemical performance of ET-B-COF, and the specific capacitance increased with the increase of the mass of carbon nanotubes added during the preparation process. Among them, ETB@CNT40 exhibits the best electrochemical performance (37.6 F g<sup>-1</sup>) at a current density of 1 A g<sup>-1</sup>. This study indicates that the simultaneous introduction of CNTs into COFs can significantly improve the electrochemical performance of ketoenamine-linked COFs materials.

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Publication Details

Journal
Macromolecular Rapid Communications
Published
2024-12-04
DOI
https://doi.org/10.1002/marc.202400829
Citations
1
Primary Topic
Covalent Organic Framework Applications
Type
article
Field-Weighted Citation Impact
0.12

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article

Integrated Carbon Nanotube and Ketoenamine‐Linked Covalent Organic Framework with Positive Charge Structure as High‐Performance Capacitive Materials

Chan Yao, Qiushi Liu, Yan-Hong Xu, Xuesong Ding et al.
1 citations
Macromolecular Rapid Communications
Covalent Organic Framework Applications
0.12
article

Integrated Carbon Nanotube and Ketoenamine‐Linked Covalent Organic Framework with Positive Charge Structure as High‐Performance Capacitive Materials

Chan Yao, Qiushi Liu, Yan-Hong Xu, Xuesong Ding, Haoyu Zhao
article en
1 citations

Abstract

A series of composite materials, ETB@CNT (ETB@CNT10, ETB@CNT20, ETB@CNT30, ETB@CNT40, ETB@CNT50) with different carbon nanotubes (CNTs) contents are successfully prepared by using one-pot method. Compared with the pure ET-B-COF, which is a ketoenamine-linked covalent organic framework (COF) with a positive charge structure, CNTs can effectively improve the electrochemical performance of ET-B-COF, and the specific capacitance increased with the increase of the mass of carbon nanotubes added during the preparation process. Among them, ETB@CNT40 exhibits the best electrochemical performance (37.6 F g<sup>-1</sup>) at a current density of 1 A g<sup>-1</sup>. This study indicates that the simultaneous introduction of CNTs into COFs can significantly improve the electrochemical performance of ketoenamine-linked COFs materials.

Macromolecular Rapid CommunicationsVol. 46(4)
Jilin Normal University (CN), National Center for Nanoscience and Technology (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 57%
Covalent Organic Framework Applications
0.12
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