Cover Feature: <i>In‐Situ</i> Electrolyte for Electrosynthesis: Scalable Anodically‐Enabled One‐Pot Sequence from Aldehyde to Isoxazol(in)es (Chem. Eur. J. 68/2024)
A straightforward transition-metal-free, one-pot electrochemical synthetic strategy toward high-value functionalized isoxazol(in)es is presented. The waste-reducing and cost-effective cascade transformation, involving “in-situ electrolyte” generation, comprises the condensation of aldehyde and NH2OH⋅HCl to an aldoxime followed by its anodic oxidation and subsequent [3+2] cycloadditions with a dipolarophile. For more insights, please refer to the Research Article by S. B. Tsogoeva, P. Nikolaienko, and co-workers (DOI: 10.1002/chem.202402696).
Authors
- Svetlana B. Tsogoeva (ORCID: https://orcid.org/0000-0003-4845-0951)
- Pavlo Nikolaienko (ORCID: https://orcid.org/0000-0002-1508-7589)
- Karl J. J. Mayrhofer (ORCID: https://orcid.org/0000-0002-4248-0431)
- Abdulaziz A. Al‐Romema
- Honglin Xia
Institutions
- Forschungszentrum Jülich (DE)
- Friedrich-Alexander-Universität Erlangen-Nürnberg (DE)
- Helmholtz Institute Erlangen-Nürnberg (DE)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2024-12-04
- DOI
- https://doi.org/10.1002/chem.202486802
- Primary Topic
- Electrocatalysts for Energy Conversion
- Type
- article
- Field-Weighted Citation Impact
- 0.00