Comprehensive Investigation of the Crystal Structure of Cation‐Disordered Li <sub>3</sub> VO <sub>4</sub> as a High‐Rate Anode Material: Unveiling the Dichotomy between Order and Disorder (Small 49/2024)
High-Performance Anode Materials In article number 2405259, Keisuke Matsumura, Etsuro Iwama, Katsuhiko Naoi, and co-workers highlight the dichotomy between order and disorder in cation-disordered materials. Extended mechanochemical treatment leads to formation of pure cation-disordered Li3VO4 crystal with enhanced electrochemical performance for ultrafast lithium-ion storage. Combination of advanced analytical techniques provides a comprehensive understanding of cationic periodicity, clearly described through an integrated superstructure model that captures transition from short-range order to long-range disorder.
Authors
- Patrice Simon (ORCID: https://orcid.org/0000-0002-0461-8268)
- Etsuro Iwama (ORCID: https://orcid.org/0000-0001-6496-4050)
- Wako Naoi
- Koji Ohara (ORCID: https://orcid.org/0000-0002-3134-512X)
- Katsuhiko Naoi (ORCID: https://orcid.org/0000-0002-0265-2235)
- Keisuke Matsumura (ORCID: https://orcid.org/0000-0001-6756-7544)
- Patrick Rozier (ORCID: https://orcid.org/0000-0002-7879-4344)
- Yuki Orikasa (ORCID: https://orcid.org/0000-0002-9869-9520)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université Toulouse III - Paul Sabatier (FR)
- Ritsumeikan University (JP)
- Shimane University (JP)
- Réseau sur le Stockage Electrochimique de l'énergie (FR)
- Centre Interuniversitaire de Recherche et d’Ingénierie des Matériaux (FR)
- Tokyo University of Agriculture and Technology (JP)
Publication Details
- Journal
- Small
- Published
- 2024-12-01
- DOI
- https://doi.org/10.1002/smll.202470367
- Primary Topic
- Advancements in Battery Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00