Portable tunable interband cascade laser spectrometer using thin-film waveguides for food contaminant analysis
Interband cascade lasers (ICL) are high output power mid-infrared light sources with low power consumption, serving as a viable alternative to more commonly applied quantum cascade lasers. The integration of ICLs with thin-film waveguides facilitates miniaturized sensing platforms based on the principles of evanescent field absorption toward tailorable high-fidelity portable mid-infrared (MIR) sensing solutions for on-site chemical analysis. The analytical performance of a MIR sensing system is presented combining a tunable interband cascade laser emitting at a wavelength range of 5.88–6.09 µm (1702–1641 cm−1) with a 6 µm GaAs/AlGaAs thin-film waveguide as the active transducer for customized evanescent field absorption analysis of food contaminants. A comparison of the analytical performance of the developed tICL-based system vs conventional Fourier-transform infrared spectroscopy is presented for the exemplary analysis of the Fusarium mycotoxin deoxynivalenol, a persistent food contaminant resulting from fungal infection. The thin-film waveguide enhances the sensitivity compared to conventional attenuated total reflection systems, revealing improved detection limits. The compact design of the system, along with the favorable analytical figures-of-merit and automated data processing, confirm the potential of the developed tICL-based spectrometer for on-site detection of food contaminants at various stages along the food supply chain.
Authors
- Antoni Femenias (ORCID: https://orcid.org/0000-0002-4005-1748)
- Mehmet Can Erdem (ORCID: https://orcid.org/0000-0003-0263-4472)
- Uladzislau Blazhko (ORCID: https://orcid.org/0000-0002-3249-950X)
- A.J. Bosman (ORCID: https://orcid.org/0000-0002-6674-7006)
- Rudolf Krska (ORCID: https://orcid.org/0000-0001-6843-9755)
- Francesco Simone Ruggeri (ORCID: https://orcid.org/0000-0002-1232-1907)
- Achim Köhler (ORCID: https://orcid.org/0000-0001-5759-1989)
- Stephan Freitag (ORCID: https://orcid.org/0000-0003-0179-2217)
- Julian Scheuermann (ORCID: https://orcid.org/0000-0003-2046-4710)
- Boris Mizaikoff (ORCID: https://orcid.org/0000-0002-5583-7962)
- Gert IJ. Salentijn (ORCID: https://orcid.org/0000-0002-2870-9084)
- Johannes Koeth
- Polina Fomina (ORCID: https://orcid.org/0000-0002-8315-7948)
- Robert Weih (ORCID: https://orcid.org/0009-0009-6414-9422)
Institutions
- Queen's University Belfast (GB)
- Albert Einstein College of Medicine (US)
- Universität Ulm (DE)
- Bioanalytica (Switzerland) (CH)
- Hahn-Schickard-Gesellschaft für angewandte Forschung (DE)
- Nanoplus (Germany) (DE)
- Norwegian University of Life Sciences (NO)
- Wageningen University & Research (NL)
- BOKU University (AT)
Publication Details
- Journal
- AIP Advances
- Published
- 2024-12-01
- DOI
- https://doi.org/10.1063/5.0226248
- Citations
- 6
- Primary Topic
- Mycotoxins in Agriculture and Food
- Type
- article
- Field-Weighted Citation Impact
- 3.60
Funders
- Science Foundation Ireland
- Norges Forskningsråd
- Horizon 2020 Framework Programme