Direct synthesis of PtNi coated with Ni<sub>3</sub>B for efficient electrochemical hydrogen evolution from seawater

The design of a protective electron-rich surface is an ideal route to enhance the performance of catalysts. Due to the higher work function of Ni<sub>3</sub>B, facile-directed electron transport occurs from PtNi to Ni<sub>3</sub>B to enrich electron density on the surface of the Ni<sub>3</sub>B shell. This process increases hydrogen adsorption-desorption kinetics and mitigates Cl<sup>-</sup> corrosion.

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Publication Details

Journal
Chemical Communications
Published
2024-12-06
DOI
https://doi.org/10.1039/d4cc04333b
Citations
3
Primary Topic
Electrocatalysts for Energy Conversion
Type
article
Field-Weighted Citation Impact
0.31

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Direct synthesis of PtNi coated with Ni3B for efficient electrochemical hydrogen evolution from seawater

Kenneth Ikechukwu Ozoemena, Yuxuan Xiao, Jie Ying, Wenying Zhao et al.
3 citations
Chemical Communications
Electrocatalysts for Energy Conversion
0.31
article

Direct synthesis of PtNi coated with Ni3B for efficient electrochemical hydrogen evolution from seawater

Kenneth Ikechukwu Ozoemena, Yuxuan Xiao, Jie Ying, Wenying Zhao, Ling Shen, Fei Yu, Christoph Janiak, Xiaoyu Yang, Song Zhang, Yang Xiong
article en
3 citations

Abstract

The design of a protective electron-rich surface is an ideal route to enhance the performance of catalysts. Due to the higher work function of Ni<sub>3</sub>B, facile-directed electron transport occurs from PtNi to Ni<sub>3</sub>B to enrich electron density on the surface of the Ni<sub>3</sub>B shell. This process increases hydrogen adsorption-desorption kinetics and mitigates Cl<sup>-</sup> corrosion.

Chemical CommunicationsVol. 61(4)
Sun Yat-sen University (CN), University of the Witwatersrand (ZA), Wuhan University of Technology (CN), Heinrich Heine University Düsseldorf (DE)
National Research Foundation, National Natural Science Foundation of China, Natural Science Foundation of Hubei Province, Key Technology Research and Development Program of Shandong, National Key Research and Development Program of China, Project 211, Basic and Applied Basic Research Foundation of Guangdong Province
Life below water
Openalex Percentile: Top 51%
Electrocatalysts for Energy Conversion
0.31
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