Formation of B2 phase and its stability in equiatomic Al-Cu-Fe-Ni-Ti high entropy alloy

In the present investigation, we have synthesized a single-phase high-entropy alloy in Al-Cu-Fe-Ni-Ti system by melting of the individual metals using a radiofrequency induction furnace under an argon environment. The as-synthesized alloy shows the formation of a B2-type ordered phase with a lattice parameter of 0.289 nm. The mechanical stability of this single phase high-entropy alloy was investigated under high-energy ball milling. The milling was performed at a speed of 400 rpm for 10, 20, and 40 h under a hexane medium with a ball-to-powder ratio of 40:1. The formation of nano crystallites (~ 10 nm sizes) body centered cubic (BCC) phase (disordered B2) has been observed after 40 h of ball milling, which has been confirmed by X-ray diffraction and transmission electron microscopic investigation. The equiatomic Al-Cu-Fe-Ni-Ti high entropy alloy structure is observed to be quite stable during mechanical milling up to 40 h; only grain refinements and lattice strain accumulation were observed with milling time. • The meticulous and precise synthesis Al-Cu-Fe-Ni-Ti high-entropy alloy alloys. • Phase Stability in Equiatomic Al-Cu-Fe-Ni-Ti B2 type high-entropy alloy. • The crystalline phase of Al-Cu-Fe-Ni-Ti high-entropy alloy is quite stable under mechanical milling. • Induction Melting and milling may be used to produce nanocrystalline HEAs with controlled sizes.