Synthesis, crystal structure and Hirshfeld surface analysis of bis(acetylacetonato-κ<sup>2</sup> <i>O</i>,<i>O</i>′)(2-amino-1-methyl-1<i>H</i>-benzimidazole-κ<i>N</i> <sup>3</sup>)copper(II)
The title compound, [Cu(C<sub>5</sub>H<sub>7</sub>O<sub>2</sub>)<sub>2</sub>(C<sub>8</sub>H<sub>9</sub>N<sub>3</sub>)], crystallizes in the ortho-rhom-bic space group <i>Pnma</i>. In the crystal structure, the Cu<sup>II</sup> ion is coordinated by two acetyl-acetonate ligands and one 2-amino-1-methyl-1<i>H</i>-benzimidazole ligand. The crystal structure features intra-molecular N-H⋯O and inter-molecular N-H⋯O hydrogen bonds, which contribute to the overall cohesion of the crystal. Hirshfeld surface analysis and two-dimensional fingerprint plots were utilized to qu-antify the inter-molecular inter-actions, revealing the relative contributions of H⋯H (61.1%), H⋯C/C⋯H (21.3%), and O⋯H/H⋯O (11.3%) contacts to the crystal packing.
Authors
- Akmaljon Tojiboev (ORCID: https://orcid.org/0000-0001-8061-0914)
- Zukhra Kadirova
- Jamshid Ashurov (ORCID: https://orcid.org/0000-0002-4441-2803)
- Shahlo Daminova (ORCID: https://orcid.org/0000-0003-2606-3221)
- Daminbek Ziyatov
- Kyzlarkhan Siddikova
Institutions
- Academy of Sciences Republic of Uzbekistan (UZ)
- Namangan State University (UZ)
- Tashkent State University of Law (UZ)
- Karshi State University (UZ)
- National University of Uzbekistan (UZ)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2024-12-03
- DOI
- https://doi.org/10.1107/s2056989024011538
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Japan International Cooperation Agency
- JST-Mirai Program