Role of obstacle softness in the diffusive behavior of active particles

We numerically investigate the diffusive behavior of active Brownian particles in a two-dimensional confined channel filled with soft obstacles, whose softness is controlled by a parameter K. Here, active particles are subjected to an external bias F. Particle diffusion is influenced by entropic barriers that arise due to variations in the shape of the chosen channel geometry. We observed that the interplay between obstacle softness, entropic barriers, and external bias leads to striking transport characteristics of the active particles. For instance, with increasing F, the non-linear mobility exhibits a non-monotonic behavior, and effective diffusion is greatly enhanced, showing multiple peaks in the presence of soft obstacles. Furthermore, as a function of K and F, particles exhibit various diffusive behaviors, e.g., normal diffusion-where the role of obstacles is insignificant, and subdiffusion or superdiffusion-where the particles are partially trapped by the obstacles, and the particles are ultimately caged by the obstacles. These findings help understand the physical situations wherein active agents diffuse in crowded environments.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2024-12-03
DOI
https://doi.org/10.1063/5.0227294
Citations
3
Primary Topic
Micro and Nano Robotics
Type
article
Field-Weighted Citation Impact
0.93

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article

Role of obstacle softness in the diffusive behavior of active particles

Poornachandra Sekhar Burada, Ankit Gupta
3 citations
The Journal of Chemical Physics
Micro and Nano Robotics
0.93
article

Role of obstacle softness in the diffusive behavior of active particles

Poornachandra Sekhar Burada, Ankit Gupta
article en
3 citations

Abstract

We numerically investigate the diffusive behavior of active Brownian particles in a two-dimensional confined channel filled with soft obstacles, whose softness is controlled by a parameter K. Here, active particles are subjected to an external bias F. Particle diffusion is influenced by entropic barriers that arise due to variations in the shape of the chosen channel geometry. We observed that the interplay between obstacle softness, entropic barriers, and external bias leads to striking transport characteristics of the active particles. For instance, with increasing F, the non-linear mobility exhibits a non-monotonic behavior, and effective diffusion is greatly enhanced, showing multiple peaks in the presence of soft obstacles. Furthermore, as a function of K and F, particles exhibit various diffusive behaviors, e.g., normal diffusion-where the role of obstacles is insignificant, and subdiffusion or superdiffusion-where the particles are partially trapped by the obstacles, and the particles are ultimately caged by the obstacles. These findings help understand the physical situations wherein active agents diffuse in crowded environments.

The Journal of Chemical PhysicsVol. 161(21)
Indian Institute of Technology Kharagpur (IN)
Science and Engineering Research Board
Sustainable cities and communities
Openalex Percentile: Top 25%
Micro and Nano Robotics
0.93
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