Doubly σ- and π-aromatic planar pentacoordinate boron polyanions
Ten planar pentacoordinate boron (ppB) systems are reported, each featuring a pentagonal ring composed of tetrels, pnictogens, or their combination around boron. These structures exhibit double aromaticity (σ and π), consistent with Hückel's 4<i>n</i>+2 rule, as confirmed by magnetically induced current density analysis.
Authors
- William Tiznado (ORCID: https://orcid.org/0000-0002-6061-8879)
- Diego Inostroza (ORCID: https://orcid.org/0000-0002-0160-0337)
- Alejandro Vásquez‐Espinal (ORCID: https://orcid.org/0000-0003-3501-7905)
- Luis Leyva‐Parra (ORCID: https://orcid.org/0000-0002-4210-1868)
- Osvaldo Yáñez (ORCID: https://orcid.org/0000-0001-8993-9353)
- Williams García-Argote (ORCID: https://orcid.org/0009-0006-6442-8059)
- Dumer S. Sacanamboy (ORCID: https://orcid.org/0000-0002-3689-3125)
Institutions
- Universidad de Santiago de Chile (CL)
- University of the Americas (CL)
- Universidad Central de Chile (CL)
- University of Chile (CL)
- Arturo Prat University (CL)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-03
- DOI
- https://doi.org/10.1039/d4cc05776g
- Citations
- 9
- Primary Topic
- Boron and Carbon Nanomaterials Research
- Type
- article
- Field-Weighted Citation Impact
- 1.05