Evaluation of the Degradation Properties of Plasma Electrolytically Oxidized Mg Alloy AZ31 Using Fluid Dynamic Accelerated Tests for Biodegradable Implants

Magnesium alloys are promising biodegradable implant materials due to their excellent biocompatibility and non-toxicity. However, their poor corrosion resistance limits their application in vivo. Plasma electrolytic oxidation (PEO) is a powerful technique to improve the corrosion resistance of magnesium alloys. In this study, we present the accelerated degradation of PEO-treated AZ31 samples using a fluid dynamic test. The samples were prepared using different concentrations of KOH as an electrolyte along with NaSiO₃. The anodizing time and the biasing time were optimized to obtain the increased corrosion resistance. The analysis of the degraded samples using microscopy, SEM EDX measurements, and by calculating mass loss and corrosion rates showed a significant increase in the corrosion resistance after the polymer (Resomer© LG 855 S) coating was applied to the anodized samples. The results confirm (or convince) that PEO treatment is an effective way to improve the corrosion resistance of AZ31 magnesium alloy. The fluid dynamic test can be used as an accelerated degradation test for biodegradable alloys in simulated body fluids at a physiological temperature. The polymer coating further improves the corrosion resistance of the PEO-treated AZ31 samples.