Rhodium(<scp>i</scp>)-catalyzed dearomative cycloisomerization of 1<i>H</i>-indole <i>N</i>-tethered <i>o</i>-alkynylphenyl nitrones and application to spirocyclic pyrido[1,2-<i>a</i>]indole synthesis
A Rh( i )-catalyzed method to prepare indoline-fused polycyclic tropanes from 1 H -indole N -tethered o -alkynylphenyl nitrone cycloisomerization and their Ce( iv )-mediated dealkylative spirocyclization is described.
Authors
- Weidong Rao (ORCID: https://orcid.org/0000-0002-6088-7278)
- Philip Wai Hong Chan (ORCID: https://orcid.org/0000-0002-8786-6143)
- Yili Shen (ORCID: https://orcid.org/0009-0001-5528-5299)
- Tianyu Lin (ORCID: https://orcid.org/0000-0002-4202-4970)
- Yongsheng Zhang (ORCID: https://orcid.org/0000-0001-7214-209X)
- Dandan Shang
Institutions
- Nanjing Forestry University (CN)
- Monash University (AU)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-12-03
- DOI
- https://doi.org/10.1039/d4qo01807a
- Citations
- 5
- Primary Topic
- Catalytic Alkyne Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.25