Intrinsic low-dielectric Cardo polyimide with high heat resistance, high transparency, and low birefringence

Low-dielectric, transparent, and high-heat-resistant polyimide (PI) films are vital for flexible electronics and high-frequency communication devices. However, balancing these properties within intrinsic polyimides remains a significant challenge. In this work, a nonplanar diamine monomer, 2,7-bis(3,5-bis(trifluoromethyl)phenyl)-9,9-bis(4-nitrophenyl)-9H-fluorene (BTFDA), containing a Cardo structure and four trifluoromethyl groups, was synthesized and copolymerized with commercial monomers to produce a series of polyimides (CPI-X). These CPI-X exhibit exceptional heat resistance, with glass transition temperatures ( T g ) exceeding 350°C, decomposition temperatures ( T d5% ) above 530°C, and low thermal expansion coefficients (CTE < 20.8 ppm/K). Additionally, they have excellent optical properties with over 92% transparency at 450 nm and low birefringence (Δ n = 0.00042). They also demonstrate good hydrophobicity with low water absorption ( M a % = 0.04%) and high-water contact angles ( C a = 97.6°). Most importantly, the CPI-X films show excellent dielectric properties ( D k = 2.25, D f = 0.00365 at 1MHz, D k = 2.13, D f = 0.0065 at 10GHz). Such intrinsic PI films with low D k values may be ideal candidates for next-generation interlayer media.