One-pot synthesis of supported sub-micron LaNi<sub>5</sub> for hydrogen storage in a carbazole-type liquid organic hydrogen carrier

Metal hydrides are promising catalysts in hydrogen-involving reactions. However, downsizing and loading metal hydrides is difficult due to their sensitivity towards oxygen and water. Here, a simple one-pot molten salt synthetical method is proposed to synthesize porous La(OH)<sub>3</sub>-supported LaNi<sub>5</sub>. The as-synthesized catalyst shows an evident improvement in catalyzing reversible hydrogen storage in liquid organic hydrogen carrier <i>N</i>-ethylcarbazole.

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Publication Details

Journal
Chemical Communications
Published
2024-12-03
DOI
https://doi.org/10.1039/d4cc05419a
Primary Topic
Hydrogen Storage and Materials
Type
article
Field-Weighted Citation Impact
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article

One-pot synthesis of supported sub-micron LaNi5 for hydrogen storage in a carbazole-type liquid organic hydrogen carrier

Hongen Yu, Yuxuan Shi, Dongsheng Geng, Jie Zheng et al.
Chemical Communications
Hydrogen Storage and Materials
article

One-pot synthesis of supported sub-micron LaNi5 for hydrogen storage in a carbazole-type liquid organic hydrogen carrier

Hongen Yu, Yuxuan Shi, Dongsheng Geng, Jie Zheng, Xingguo Li, Zewei Xie, Rumei Jin, Youyu Lin
article en

Abstract

Metal hydrides are promising catalysts in hydrogen-involving reactions. However, downsizing and loading metal hydrides is difficult due to their sensitivity towards oxygen and water. Here, a simple one-pot molten salt synthetical method is proposed to synthesize porous La(OH)<sub>3</sub>-supported LaNi<sub>5</sub>. The as-synthesized catalyst shows an evident improvement in catalyzing reversible hydrogen storage in liquid organic hydrogen carrier <i>N</i>-ethylcarbazole.

Chemical CommunicationsVol. 61(4)
Nanjing University of Information Science and Technology (CN), Peking University (CN), Nanjing University of Science and Technology (CN), Beijing National Laboratory for Molecular Sciences (CN)
Openalex Percentile: Top 86%
Hydrogen Storage and Materials
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