Selective Hydrothermal Leaching of Aluminum from Al<sub>3</sub>YRh<sub><i>x</i></sub> (<i>x</i> = 0, 0.2, 0.5, 1.0) Intermetallic Compounds: The Effect of Rh Variants in Comparing the Catalytic CO Oxidation and CO-PROX Reactions

Wealth from modern civilization and globalization accelerates natural resource extraction and damages the Earth's environment. Elevated mute assassin "carbon monoxide (CO)" levels impede aerobic life. We need to develop limiting technologies to overcome these constraints. Stern environmental agreements to reduce CO levels are significant. In this work, a hydrothermal leaching (HyTL) of Al<sub>3</sub>Y-Rh <sub><i>x</i></sub> (<i>x</i> = 0, 0.2, 0.5, 1.0) intermetallic compounds yields Y(OH)<sub>3</sub> products with well-distributed rhodium (Rh). The HyTL method and active Rh element improved HyTL Al<sub>3</sub>Y-Rh<sub>0.5</sub> catalytic CO oxidation and the preferential oxidation of the CO (CO-PROX) performance. Metal-support interactions and HyTL Al<sub>3</sub>Y-Rh<sub>0.5</sub> catalyst synergy produce oxygen vacancies, govern CO oxidation, and standardize oxygen mobility. This is essential to the synthesized catalyst's improved catalytic performance. All low-temperature instances of Rh have strong catalytic activity. This study advances CO catalytic oxidation and CO-PROX over the HyTL Al<sub>3</sub>Y-Rh<sub>0.5</sub> catalyst, ensuring the aggregation-activation process. The findings support an understanding of low-temperature catalytic systems.

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Journal
ACS Materials Au
Published
2024-11-29
DOI
https://doi.org/10.1021/acsmaterialsau.4c00140
Primary Topic
Catalytic Processes in Materials Science
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article
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0.00

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article

Selective Hydrothermal Leaching of Aluminum from Al3YRhx (x = 0, 0.2, 0.5, 1.0) Intermetallic Compounds: The Effect of Rh Variants in Comparing the Catalytic CO Oxidation and CO-PROX Reactions

Satoshi Kameoka, Balasubramanian Sriram, Sea‐Fue Wang
ACS Materials Au
Catalytic Processes in Materials Science
article

Selective Hydrothermal Leaching of Aluminum from Al3YRhx (x = 0, 0.2, 0.5, 1.0) Intermetallic Compounds: The Effect of Rh Variants in Comparing the Catalytic CO Oxidation and CO-PROX Reactions

Satoshi Kameoka, Balasubramanian Sriram, Sea‐Fue Wang
article en

Abstract

Wealth from modern civilization and globalization accelerates natural resource extraction and damages the Earth's environment. Elevated mute assassin "carbon monoxide (CO)" levels impede aerobic life. We need to develop limiting technologies to overcome these constraints. Stern environmental agreements to reduce CO levels are significant. In this work, a hydrothermal leaching (HyTL) of Al<sub>3</sub>Y-Rh <sub><i>x</i></sub> (<i>x</i> = 0, 0.2, 0.5, 1.0) intermetallic compounds yields Y(OH)<sub>3</sub> products with well-distributed rhodium (Rh). The HyTL method and active Rh element improved HyTL Al<sub>3</sub>Y-Rh<sub>0.5</sub> catalytic CO oxidation and the preferential oxidation of the CO (CO-PROX) performance. Metal-support interactions and HyTL Al<sub>3</sub>Y-Rh<sub>0.5</sub> catalyst synergy produce oxygen vacancies, govern CO oxidation, and standardize oxygen mobility. This is essential to the synthesized catalyst's improved catalytic performance. All low-temperature instances of Rh have strong catalytic activity. This study advances CO catalytic oxidation and CO-PROX over the HyTL Al<sub>3</sub>Y-Rh<sub>0.5</sub> catalyst, ensuring the aggregation-activation process. The findings support an understanding of low-temperature catalytic systems.

ACS Materials AuVol. 5(3)
National Taipei University of Technology (TW), Tohoku University (JP)
Tohoku University, National Taipei University of Technology
Openalex Percentile: Top 86%
Catalytic Processes in Materials Science
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Selective Hydrothermal Leaching of Aluminum from Al<sub>3</sub>YRh<sub><i>x</i></sub> (<i>x</i> = 0, 0.2, 0.5, 1.0) Intermetallic Compounds: The Effect of Rh Variants in Comparing the Catalytic CO Oxidation and CO-PROX Reactions — Satoshi Kameoka, Balasubramanian Sriram, et al. · ACS Materials Au (2024) | TGRS Research Map | TGRS