Mechanocaloric Effects Characterization of Low-Crystalline Thermoplastic Polyurethanes Fiber

Mechanocaloric cooling/heat pumping with zero carbon emission and high efficiency shows great potential for replacing traditional refrigeration with vapor compression. Mechanocaloric prototypes that are developed using shape memory alloys (SMAs) face the problems of a large driving force and high cost. In this work, we report a low-crystalline thermoplastic polyetherurethane (TPU) elastomer fiber with a low actuation force and good mechanocaloric performance. We fabricate the TPU fiber and develop a multifunctional mechanical tester to measure both the elastocaloric and twistocaloric effects. In the experiments, the applied stress required to induce mechanocaloric effects of the TPU fiber is only 10~30 MPa, which is much lower than that of widely used NiTi elastocaloric SMAs (600~1200 MPa). The TPU fiber produces a maximum twistocaloric adiabatic temperature change of 10.2 K, which is 78.9% larger than its elastocaloric effect of 5.7 K. The wide-angle X-ray scattering (WAXS) results show that the strain-induced amorphous chain alignment and associated configurational entropy change are the main causes of the good mechanocaloric effects of the TPU fiber, rather than the strain-induced crystallization. This work demonstrates the potential of achieving low-force heat-efficient mechanocaloric cooling using thermoplastic elastomer fibers.