From structure to electrochemistry: the influence of transition metal ordering on Na<sup>+</sup>/vacancy orderings in P2-type Na<sub><i>x</i></sub>MO<sub>2</sub> cathode materials for sodium-ion batteries
In this work, the origin of Na + /vacancy orderings in P2-type Na x Ni y Mn 1− y O 2 is investigated. A general guideline to suppress Na + /vacancy orderings in P2-type Na x MO 2 cathode active materials is postulated.
Authors
- Maider Zarrabeitia (ORCID: https://orcid.org/0000-0003-1305-2136)
- Daria Mikhailova (ORCID: https://orcid.org/0000-0002-8197-1807)
- Manuel Dillenz (ORCID: https://orcid.org/0000-0002-4901-154X)
- Daniel Roscher
- Mohsen Sotoudeh (ORCID: https://orcid.org/0000-0002-0970-5336)
- Lukas Fridolin Pfeiffer (ORCID: https://orcid.org/0000-0002-7473-7326)
- Margret Wohlfahrt‐Mehrens (ORCID: https://orcid.org/0000-0002-5118-5215)
- Michael Busch (ORCID: https://orcid.org/0000-0003-3883-2868)
- Volodymyr Baran (ORCID: https://orcid.org/0000-0003-2379-3632)
- Ahmad Omar (ORCID: https://orcid.org/0000-0001-6759-2053)
- Peter Axmann (ORCID: https://orcid.org/0000-0003-0274-1796)
- Přemysl Beran (ORCID: https://orcid.org/0000-0002-1217-3131)
- Stefano Passerini (ORCID: https://orcid.org/0000-0002-6606-5304)
- Axel Groß (ORCID: https://orcid.org/0000-0003-4037-7331)
- Charles H. Hervoches (ORCID: https://orcid.org/0000-0002-9550-3289)
- Nora Burgard
- Paul Drews
- Neelima Paul
Institutions
- Karlsruhe Institute of Technology (DE)
- Luleå University of Technology (SE)
- European Spallation Source (SE)
- Deutsches Elektronen-Synchrotron DESY (DE)
- Leibniz Institute for Solid State and Materials Research (DE)
- Heinz Maier-Leibnitz Zentrum (DE)
- Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg (DE)
- Helmholtz-Institute Ulm (DE)
- Czech Academy of Sciences, Nuclear Physics Institute (CZ)
- Technical University of Munich (DE)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2024-11-28
- DOI
- https://doi.org/10.1039/d4ta04786a
- Citations
- 19
- Primary Topic
- Advancements in Battery Materials
- Type
- article
- Field-Weighted Citation Impact
- 3.96
Funders
- Deutsche Forschungsgemeinschaft
- Ministerstvo Školství, Mládeže a Tělovýchovy
- Bundesministerium für Bildung und Forschung
- Helmholtz Association
- Deutsches Elektronen-Synchrotron