Chiral ruthenium porphyrin-catalyzed asymmetric cyclopropanation of 1,3-dienes with <i>tert</i>-butyl 2-cyano-2-diazoacetate as the carbene source
With the chiral ruthenium porphyrin complex ( S , R )-cmcpor-RuCO as a catalyst and tert -butyl 2-cyano-2-diazoacetate as the carbene source, a panel of substituted vinylcyclopropanes is readily prepared in good product yields and high enantioselectivity.
Authors
- Chi‐Ming Che (ORCID: https://orcid.org/0000-0002-2554-7219)
- Yungen Liu (ORCID: https://orcid.org/0000-0002-2473-6173)
- Siqi Zhong
- Hao‐Chong Tan
- Huahua Wang (ORCID: https://orcid.org/0009-0007-7624-4895)
Institutions
- Southern University of Science and Technology (CN)
- State Key Laboratory of Synthetic Chemistry (CN)
- University of Hong Kong (HK)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-11-28
- DOI
- https://doi.org/10.1039/d4qo01576b
- Citations
- 2
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.50
Funders
- National Natural Science Foundation of China
- Innovation and Technology Commission
- Southern University of Science and Technology