Pivotal role of solid phase interactions in the pressure-induced bi-stability of cyanide-bridged Fe <sub>2</sub> Co <sub>2</sub> square complexes
Pressure-sensitive (Fe–CN–Co) molecular switches can be obtained by controlling the crystallization temperature. Here, an intriguing conversion from Fe III –Co II to Fe II –Co III and back to Fe III –Co II upon increasing pressure at 200 K is rationalized.
Authors
- Geoffrey Gontard (ORCID: https://orcid.org/0000-0002-4099-5423)
- Rodrigue Lescouëzec (ORCID: https://orcid.org/0000-0003-3510-5112)
- Maxime Deutsch (ORCID: https://orcid.org/0000-0001-7111-1187)
- Keevin Béneut
- Paraskevas Parisiades (ORCID: https://orcid.org/0000-0001-6962-264X)
- Yanling Li (ORCID: https://orcid.org/0000-0002-0144-5664)
- Buqin Xu
Institutions
- Centre National de la Recherche Scientifique (FR)
- Sorbonne Université (FR)
- Laboratoire de Cristallographie, Résonance Magnétique et Modélisations (FR)
- Institut de minéralogie, de physique des matériaux et de cosmochimie (FR)
- Institut Parisien de Chimie Moléculaire (FR)
- Université de Lorraine (FR)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2024-11-27
- DOI
- https://doi.org/10.1039/d4qi02499k
- Citations
- 2
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.24
Funders
- Université de Lorraine