A catalyst- and solvent-free visible-light-promoted bromination and chlorination of tertiary C(sp<sup>3</sup>)–H bonds
We report herein a visible-light-driven bromination/chlorination of 3° C(sp 3 )–H bonds without using any catalyst or solvent. This method features high site selectivity, scalability and excellent functional group tolerance, even in complex molecules.
Authors
- Quanjin Rong
- Jie Meng (ORCID: https://orcid.org/0000-0003-0184-4136)
- Fan Wang (ORCID: https://orcid.org/0000-0003-3674-1292)
- Zhe Zhang (ORCID: https://orcid.org/0000-0002-7510-9559)
- Zhong‐Quan Liu (ORCID: https://orcid.org/0000-0001-6961-0585)
Institutions
- Nanjing University of Chinese Medicine (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-11-27
- DOI
- https://doi.org/10.1039/d4qo01997k
- Citations
- 5
- Primary Topic
- Vanadium and Halogenation Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.79