Simple Fluctuations in Simple Glass Formers

Critical single-particle fluctuations associated with particle displacements are inherent to simple glass-forming liquids in the limit of large dimensions and leave a pseudocritical trace across all finite dimensions. This characteristic could serve as a crucial test for distinguishing between theories of glass formation. We here examine these critical fluctuations, as captured by the well-established non-Gaussian parameter, within both mode-coupling theory (MCT) and dynamical mean-field theory (DMFT) across dimensions for hard sphere fluids and for the minimally structured Mari-Kurchan model. We establish general scaling laws relevant to any liquid dynamics theory in large dimensions and show that the dimensional scalings predicted by MCT are inconsistent with those from DMFT. Simulation results for hard sphere fluids in moderately high dimensions align with the DMFT scenario, reinforcing the relevance of mean-field theory for capturing glass physics in finite dimensions. We identify potential adjustments to MCT to account for certain mean-field physics. Our findings also highlight that local structure and spatial dimensionality can affect single-particle critical fluctuations in nontrivial ways.

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Publication Details

Journal
The Journal of Physical Chemistry B
Published
2024-11-26
DOI
https://doi.org/10.1021/acs.jpcb.4c05447
Citations
2
Primary Topic
Material Dynamics and Properties
Type
article
Field-Weighted Citation Impact
0.23

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article

Simple Fluctuations in Simple Glass Formers

Liesbeth M. C. Janssen, Yi Hu, Grzegorz Szamel, Ilian Pihlajamaa et al.
2 citations
The Journal of Physical Chemistry B
Material Dynamics and Properties
0.23
article

Simple Fluctuations in Simple Glass Formers

Liesbeth M. C. Janssen, Yi Hu, Grzegorz Szamel, Ilian Pihlajamaa, Patrick Charbonneau, Corentin C. L. Laudicina, Peter K. Morse
article en
2 citations

Abstract

Critical single-particle fluctuations associated with particle displacements are inherent to simple glass-forming liquids in the limit of large dimensions and leave a pseudocritical trace across all finite dimensions. This characteristic could serve as a crucial test for distinguishing between theories of glass formation. We here examine these critical fluctuations, as captured by the well-established non-Gaussian parameter, within both mode-coupling theory (MCT) and dynamical mean-field theory (DMFT) across dimensions for hard sphere fluids and for the minimally structured Mari-Kurchan model. We establish general scaling laws relevant to any liquid dynamics theory in large dimensions and show that the dimensional scalings predicted by MCT are inconsistent with those from DMFT. Simulation results for hard sphere fluids in moderately high dimensions align with the DMFT scenario, reinforcing the relevance of mean-field theory for capturing glass physics in finite dimensions. We identify potential adjustments to MCT to account for certain mean-field physics. Our findings also highlight that local structure and spatial dimensionality can affect single-particle critical fluctuations in nontrivial ways.

The Journal of Physical Chemistry BVol. 128(49)
Duke University (US), Princeton University (US), Eindhoven University of Technology (NL), Colorado State University (US)
Simons Foundation, Nederlandse Organisatie voor Wetenschappelijk Onderzoek, Division of Chemistry
Sustainable cities and communities
Openalex Percentile: Top 50%
Material Dynamics and Properties
0.23
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Simple Fluctuations in Simple Glass Formers — Liesbeth M. C. Janssen, Yi Hu, et al. · The Journal of Physical Chemistry B (2024) | TGRS Research Map | TGRS