2D Ti3C2Tx-MXene and its superstructures as dual-function electrodes for triboelectric nanogenerators for self-powered electronics

• Layer-by-layer stacked vertical CS mode BW-TENG was fabricated. • Multi-layered superstructures of TiO 2 /PVA were used as tribonegative layer. • The output power density of 5.66 W·m −2 was observed with a loading of 10 MΩ. • Humidity sensing characteristics due to layered MXene stacked structure. • BW-TENG showed biomechanical energy harvesting and self-powered sensing. Selecting distinct materials to design a tribopositive and tribonegative electrode pair for a triboelectric nanogenerator (TENG) device is a challenging task, as the interfacial electric field causes surface charges to diffuse into the air or within the material itself, leads to charge deterioration. To address these challenges, there is a strong demand for engineered materials and electrode designs that enable effective charge accumulation and trapping to regulate their performance optimally. Herein, we introduce a unique electrode design for a contact-separation (CS) mode triboelectric nanogenerator TENG featuring multilayered Ti 3 C 2 T x MXene/Kapton as tribonegative electrodes. For the tribopositive electrode, we developed an innovative synthesis strategy to create MXene-seeded layered TiO 2 superstructures/PVA-based tribopositive electrodes. After optimization of both triboelectric layers, the optimized TENG showed an open-circuit voltage ( V oc ) ∼ 120 V, short-circuit current ( I sc ) ∼ 25 μA, and power density of 5.66 W·m −2 . The surface terminations groups in highly conductive black MXene nanosheets and the oxygen vacancies in TiO 2 -layered superstructures provide abundant charge accumulation and trapping sites due to organized multilayered structures at both ends. Moreover, the induced polarization in the tribopositive layer due to the hybrid film could further hinder the free electrons’ drift to the bottom electrode, preventing charge recombination. The optimized TENG was tested as a pressure sensor to monitor different sensitive physiological movements of the human body. Further application of the designed TENG has been revealed by humidity sensing characteristics, powering LEDs, stopwatches, pedometers, and swiftly charging micro-capacitors by utilizing direct output power. By employing a controlled synthesis strategy, our approach leverages the unique properties of MXenes to function as both tribo-positive and tribonegative electrodes within the same device. This dual-function capability simplifies material selection and enhances overall device performance, presenting a transformative solution for next-generation TENG applications.