ELECTRONIC EFFECTS OF XENON-CONTAINING SUBSTITUENTS

The electronic effects of xenon-containing substituents XeY, [Xe+] and [XeF+2] in different solvents were calculated using the 19F NMR method. The results obtained allow us to classify these substituents as the strongest σ-electron acceptors due to the strong positive inductive effect, while the resonance effect is small.

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Journal
Химия в интересах устойчивого развития
Published
2024-08-31
DOI
https://doi.org/10.15372/csd2024577
Primary Topic
Organic Chemistry Cycloaddition Reactions
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article
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article

ELECTRONIC EFFECTS OF XENON-CONTAINING SUBSTITUENTS

BARDIN V.V.
Химия в интересах устойчивого развития
Organic Chemistry Cycloaddition Reactions
article

ELECTRONIC EFFECTS OF XENON-CONTAINING SUBSTITUENTS

BARDIN V.V.
article en

Abstract

The electronic effects of xenon-containing substituents XeY, [Xe+] and [XeF+2] in different solvents were calculated using the 19F NMR method. The results obtained allow us to classify these substituents as the strongest σ-electron acceptors due to the strong positive inductive effect, while the resonance effect is small.

Химия в интересах устойчивого развитияVol. 32(4)
Novosibirsk Institute of Organic Chemistry (RU)
Openalex Percentile: Top 84%
Organic Chemistry Cycloaddition Reactions
DOISourceOpenAlex
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ELECTRONIC EFFECTS OF XENON-CONTAINING SUBSTITUENTS — BARDIN V.V. · Химия в интересах устойчивого развития (2024) | TGRS Research Map | TGRS