An MgV<sub>3</sub>O<sub>8</sub> anode exhibiting enhanced rate capability and stability for lithium storage applications

The development of anode materials with high rate performance as well as favourable working durability is key for next-generation lithium-ion batteries (LIBs). Here, MgV<sub>3</sub>O<sub>8</sub> is reported as an advanced anode material, using a facile and scalable solution combustion technology. The MgV<sub>3</sub>O<sub>8</sub> anode shows a "near-zero" volume change (<10% over 1000 cycles). This can be explained by a solid-solution Li<sup>+</sup> storage mechanism, leading to superior cycling stability. Consequently, the MgV<sub>3</sub>O<sub>8</sub> electrode achieves a remarkable capacity of approximately 102.6 mA h g<sup>-1</sup> at 2.0 A g<sup>-1</sup>, along with a low fading rate of 0.001% per cycle over 3000 cycles.

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Publication Details

Journal
Chemical Communications
Published
2024-11-26
DOI
https://doi.org/10.1039/d4cc05716c
Citations
2
Primary Topic
Advancements in Battery Materials
Type
article
Field-Weighted Citation Impact
0.42
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article

An MgV3O8 anode exhibiting enhanced rate capability and stability for lithium storage applications

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article

An MgV3O8 anode exhibiting enhanced rate capability and stability for lithium storage applications

Qingchun Zhang, Yingze Song, Henghui Xu, Zhiqin Cao, Jie Zhao, Qi Wan, Wenshu Li, Xijun Wei, Yu Liu, Xun Xu
article en
2 citations

Abstract

The development of anode materials with high rate performance as well as favourable working durability is key for next-generation lithium-ion batteries (LIBs). Here, MgV<sub>3</sub>O<sub>8</sub> is reported as an advanced anode material, using a facile and scalable solution combustion technology. The MgV<sub>3</sub>O<sub>8</sub> anode shows a "near-zero" volume change (<10% over 1000 cycles). This can be explained by a solid-solution Li<sup>+</sup> storage mechanism, leading to superior cycling stability. Consequently, the MgV<sub>3</sub>O<sub>8</sub> electrode achieves a remarkable capacity of approximately 102.6 mA h g<sup>-1</sup> at 2.0 A g<sup>-1</sup>, along with a low fading rate of 0.001% per cycle over 3000 cycles.

Chemical CommunicationsVol. 61(4)
Southwest University of Science and Technology (CN), Panzhihua University (CN)
Affordable and clean energy
Openalex Percentile: Top 36%
Advancements in Battery Materials
0.42
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