Three New Hydrogenosuccinate and Succinate AdductsComplexes: Synthesis and SpectroscopicStudy

One new hydrogenosuccinate and two succinate adduct and complex have been synthesized and studied by infrared, UV-Visible and NMR (Nuclear Magnetic Resonance Spectroscopy) 119 Sn spectroscopies.The suggested structure is discrete, the hydrogenosuccinate behaving as a monodentate ligand or only involved in hydrogen bonding, the environment around the magnesium centre being triangular (compound 3).The succiate anion is a monochelating ligand (compound 1 and 2).In all the suggested structures, when extra hydrogen bonds are considered, supramolecular architectures are obtained (compound 2 and 3).

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Publication Details

Journal
Journal of Environmental Science and Engineering - A
Published
2024-11-26
DOI
https://doi.org/10.17265/2162-5298/2024.06.003
Primary Topic
Inorganic and Organometallic Chemistry
Type
article
Field-Weighted Citation Impact
0.00

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article

Three New Hydrogenosuccinate and Succinate AdductsComplexes: Synthesis and SpectroscopicStudy

Waly Diallo, Cheikh Diop, Mamadou Sidibé, Bocar Traoré et al.
Journal of Environmental Science and Engineering - A
Inorganic and Organometallic Chemistry
article

Three New Hydrogenosuccinate and Succinate AdductsComplexes: Synthesis and SpectroscopicStudy

Waly Diallo, Cheikh Diop, Mamadou Sidibé, Bocar Traoré, Daouda Ndoye, BoucarDiouf
article en

Abstract

One new hydrogenosuccinate and two succinate adduct and complex have been synthesized and studied by infrared, UV-Visible and NMR (Nuclear Magnetic Resonance Spectroscopy) 119 Sn spectroscopies.The suggested structure is discrete, the hydrogenosuccinate behaving as a monodentate ligand or only involved in hydrogen bonding, the environment around the magnesium centre being triangular (compound 3).The succiate anion is a monochelating ligand (compound 1 and 2).In all the suggested structures, when extra hydrogen bonds are considered, supramolecular architectures are obtained (compound 2 and 3).

Journal of Environmental Science and Engineering - AVol. 13(6)
Cheikh Anta Diop University (SN)
Université de Bourgogne, Centre National de la Recherche Scientifique
Zero hunger
Openalex Percentile: Top 84%
Inorganic and Organometallic Chemistry
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