Entropy optimized radiative boundary layer flow and heat-mass transfer of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si1.svg"> <mml:mrow> <mml:mi>A</mml:mi> <mml:mi>g</mml:mi> <mml:mo linebreak="goodbreak" linebreakstyle="after"

The study of boundary layer flow (BLF) with heat-mass transfer of binary chemical processes and nanofluids (NF) over a wedge is essential for improving heat transfer and reaction kinetics in applications including processing of material technologies, chemical reactors, and energy-efficient cooling mechanisms. This paper examines the entropy optimized BLF of silver A g − water based nanofluid with binary chemical species over a wedge surface. The Tiwari-Das model is executed in this model which account the load of A g − nanomaterials. The flow of NF over a moving wedge subject to favorable and adverse pressure differential is addressed by Naiver-Stokes equation. This model accounts the homogeneous heat reaction, viscous dissipation, joule heating and thermal radiations. The dimensionless equations for flow, for heat, and concentration are formulated and solved numerically using the fourth ordered Rung-Kutta approach. The findings suggest that fluid concentration is lowered with a rise in Schmidt number and homogenous chemical reaction. Thermal distribution improve with heterogonous reaction, magnetic parameter and deteriorate with wedge parameter. The skin friction rises from 25.277 % to 26.455 % with a material load of 3 % and magnetic parameter. The Nusselt decline with a radiative parameter from 10.984 % to 2.9748 % when particle load of 3 % is accounted.