Robust phosphine-based covalent-organic framework palladium catalysts for the highly efficient carbonylation coupling reaction
The first vinyl-linked PPh<sub>3</sub>-based covalent-organic frameworks (Pd@TMBen-PPh<sub>3</sub> and Pd@TMBen-4F-PPh<sub>3</sub>) were facilely constructed <i>via</i> direct three-component Knoevenagel condensation, which could serve as outstanding heterogeneous catalysts for the Pd-catalyzed carbonylation coupling reaction owing to the synergistic effect of the flexible PPh<sub>3</sub>-ligated Pd complexes and the rigid framework.
Authors
- Jianhan Huang (ORCID: https://orcid.org/0000-0002-3838-0622)
- You‐Nian Liu (ORCID: https://orcid.org/0000-0002-7078-5937)
- Liuqing He (ORCID: https://orcid.org/0000-0003-0213-3213)
- Jiawei Li (ORCID: https://orcid.org/0000-0001-5646-198X)
- You Wang (ORCID: https://orcid.org/0000-0001-6470-4646)
- Benling Yu
- Juan Zhong (ORCID: https://orcid.org/0000-0002-1524-5946)
- Shiyuan Wei (ORCID: https://orcid.org/0009-0003-4069-8909)
Institutions
- Central South University (CN)
- Second Xiangya Hospital of Central South University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-11-26
- DOI
- https://doi.org/10.1039/d4cc05624h
- Citations
- 2
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.23
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Hunan Province