Ammonium Oxathioamidate
Ammonium oxathioamidate (1) was synthesised by the reaction between O-ethyl-thioxamate (oxalic acid-1-amide-2-O-ethyl ester) and ammonium hydrogen carbonate in water solution. Compound 1 was fully characterised by both microanalytical (elemental analysis, melting point determination) and spectroscopic means (FT-IR and NMR spectroscopy). Crystals suitable for single-crystal X-ray diffraction were isolated by slow evaporation of an ethanol solution of the compound. The analysis of the crystal packing reveals the prominent role exerted by intermolecular hydrogen bonding (HB) and chalcogen bonding (ChB) interactions.
Authors
- Anna Pintus (ORCID: https://orcid.org/0000-0001-6069-9771)
- David B. Cordes (ORCID: https://orcid.org/0000-0002-5366-9168)
- M. Carla Aragoni (ORCID: https://orcid.org/0000-0002-5010-7370)
- Alexandra M. Z. Slawin (ORCID: https://orcid.org/0000-0002-9527-6418)
- Massimiliano Arca (ORCID: https://orcid.org/0000-0002-0058-6406)
- Enrico Podda (ORCID: https://orcid.org/0000-0002-4329-7751)
- J. Derek Woollins (ORCID: https://orcid.org/0000-0002-1498-9652)
- Riccardo Serra
Institutions
- University of St Andrews (GB)
- University of Cagliari (IT)
Publication Details
- Journal
- Molbank
- Published
- 2024-11-26
- DOI
- https://doi.org/10.3390/m1924
- Primary Topic
- Synthesis and Characterization of Heterocyclic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Università degli Studi di Cagliari
- Fondazione di Sardegna