Cover Feature: Migration of <i>para</i>‐Nitrophenyl Groups in Methyl Pyranosides: Configuration and Conformation Determine the Kinetics (Chem. Eur. J. 66/2024)

The Cover Feature shows a race between different sugars in which a para-nitrophenyl (PNP) substituent must be transferred from the start to the finish line. The rate constants of the substituents′ migration are represented by animals (and a stone). The track itself has a bump that represents the energy barrier of the migration. Thus, the cover sums up our work investigating PNP migration for different sugars, which yielded the rate constants and energy barriers. We also performed theoretical studies on the mechanism and its energetic profile. More information can be found in the Research Article by L. M. Friedrich, C. Lütjohann, B. Hartke and T. K. Lindhorst (DOI: 10.1002/chem.202403117).

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Publication Details

Journal
Chemistry - A European Journal
Published
2024-11-26
DOI
https://doi.org/10.1002/chem.202486604
Primary Topic
Chemical Reaction Mechanisms
Type
article
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article

Cover Feature: Migration of para‐Nitrophenyl Groups in Methyl Pyranosides: Configuration and Conformation Determine the Kinetics (Chem. Eur. J. 66/2024)

Thisbe K. Lindhorst, Bernd Hartke, Clemens Lütjohann, Leon M. Friedrich
Chemistry - A European Journal
Chemical Reaction Mechanisms
article

Cover Feature: Migration of para‐Nitrophenyl Groups in Methyl Pyranosides: Configuration and Conformation Determine the Kinetics (Chem. Eur. J. 66/2024)

Thisbe K. Lindhorst, Bernd Hartke, Clemens Lütjohann, Leon M. Friedrich
article en

Abstract

The Cover Feature shows a race between different sugars in which a para-nitrophenyl (PNP) substituent must be transferred from the start to the finish line. The rate constants of the substituents′ migration are represented by animals (and a stone). The track itself has a bump that represents the energy barrier of the migration. Thus, the cover sums up our work investigating PNP migration for different sugars, which yielded the rate constants and energy barriers. We also performed theoretical studies on the mechanism and its energetic profile. More information can be found in the Research Article by L. M. Friedrich, C. Lütjohann, B. Hartke and T. K. Lindhorst (DOI: 10.1002/chem.202403117).

Chemistry - A European JournalVol. 30(66)
Christian-Albrechts-Universität zu Kiel (DE)
Openalex Percentile: Top 84%
Chemical Reaction Mechanisms
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