Development and Characterization of Alkali-Activated Lithium Slag-Fly Ash Composite Cement

As the demand for environmental sustainability grows in the global construction industry, traditional cement production faces significant challenges due to high energy consumption and substantial CO2 emissions. Therefore, developing low-carbon, high-performance alternative cementitious materials has become a research focus. This paper proposes a new low-carbon cement (alkali-activated lithium slag-fly ash composite cement, ALFC) as a substitute for traditional cement. First, the alkali activation reactivity of lithium slag (LS) is enhanced through calcination and grinding, revealing the reasons behind its improved reactivity. Then, alkali-activated LS and fly ash were partially used to replace cement to prepare ALFC, and the effects of the water-to-binder ratio (W/B), LS content, and NaOH addition on the flowability and mechanical properties of ALFC were investigated. XRD, SEM/EDS, and TG/DTG analyses were conducted to examine its hydration products and microstructure, revealing the hydration mechanism. The results show that the flowability of ALFC increases with W/B but decreases with a higher LS content. When W/B is 0.325 and the LS content is 25 wt.%, flowability reaches 200 mm, meeting construction requirements. LS calcined at 700 °C for 1 h significantly enhanced ALFC’s 90-day flexural and compressive strengths by 39.73% and 58.47%, respectively. The primary hydration products of ALFC are C-S-H, N-A-S-H, and C-A-S-H gels, with their content increasing as the NaOH concentration rises. The optimal NaOH concentration and LS content for ALFC are 2 mol/L and 25 wt.%, respectively.