Bamboo Kraft Pulp Black Liquor as a Renewable Source of Value-Added Carbon Dots
China is the country with the most abundant bamboo resources in the world. Using bamboo as a raw material for pulping and papermaking can save a lot of wood and protect forests. Bamboo pulping enterprises mostly adopt sulfate processes to produce a large amount of black liquor (BL), which contains monosaccharides, polysaccharides, oligosaccharides, pectin, lignin, etc. The utilization of the high-value organic matter is of great economic and environmental significance. In this study, blue-green carbon dots (C-dots) were prepared from bamboo (<i>Lingnania chungii</i>) kraft pulp BL using a hydrothermal method. The changes in carbohydrate content in BL in relation to hydrothermal temperature and hydrothermal time were discussed in detail. Then, a series of characterizations of BL-C-dots, prepared under one of the hydrothermal conditions (180 °C, 6 h), were performed and the BL-C-dots showed an excitation-dependent photoluminescence (PL) spectrum and a quantum yield (QY) of 2.9% in an aqueous solution. Finally, the as-prepared BL-C-dots were successfully used as fluorescent materials to develop an anti-counterfeiting code. The fluorescent code exhibited a clear outline, an excitation-tunable color, good stability, and high security, showing great anti-counterfeiting potential and realizing the high-value utilization of BL.
Authors
- Guangting Han (ORCID: https://orcid.org/0000-0002-5165-8166)
- Xiaolong Qiao (ORCID: https://orcid.org/0000-0003-0648-0570)
- Yan Song (ORCID: https://orcid.org/0000-0003-0145-8585)
- Wei Jiang (ORCID: https://orcid.org/0000-0003-4316-880X)
- Haoxi Ben (ORCID: https://orcid.org/0000-0002-0569-9397)
- Haiguang Zhao (ORCID: https://orcid.org/0000-0003-1057-9522)
- Shixing Wang (ORCID: https://orcid.org/0000-0001-5979-2995)
- Qiulian Liu
- Yuanming Zhang (ORCID: https://orcid.org/0009-0003-8722-644X)
Institutions
- Qingdao University (CN)
- Dezhou University (CN)
Publication Details
- Journal
- Nanomaterials
- Published
- 2024-11-23
- DOI
- https://doi.org/10.3390/nano14231887
- Citations
- 4
- Primary Topic
- Interconnection Networks and Systems
- Type
- article
- Field-Weighted Citation Impact
- 1.40
Funders
- Department of Science and Technology of Shandong Province
- Department of Education of Shandong Province
- Dezhou University
- Natural Science Foundation of Shandong Province
- Qingdao University
- Wuhan Textile University