Crystalline potassium boryl dithiolate and diselenolate
Both the B-S and S-S bonds of 1,2,4,3,5-trithiadiborolane 1 could be cleaved by potassium graphite (KC<sub>8</sub>) to give the first isolable boryl dithiolate DmpB(SK)<sub>2</sub>3, whereas the reduction of 1,2,4-triselena-3,5-diborolane 2 with KC<sub>8</sub> afforded the boryl diselenolate DmpB(SeK)(SeSeK) 4, showcasing the unprecedented structural authentication of ligand substituted diselenolate.
Authors
- Qian‐Li Li (ORCID: https://orcid.org/0000-0002-2191-1191)
- Yuyang Dai
- Lingbing Kong (ORCID: https://orcid.org/0000-0002-8830-2462)
- Liliang Wang (ORCID: https://orcid.org/0000-0003-2079-6539)
- Yu Wang (ORCID: https://orcid.org/0000-0002-3883-5578)
- Fan Qi
Institutions
- Shandong University (CN)
- Hangzhou Normal University (CN)
- Liaocheng University (CN)
- University of Jinan (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-11-25
- DOI
- https://doi.org/10.1039/d4cc05240d
- Primary Topic
- Organic and Molecular Conductors Research
- Type
- article
- Field-Weighted Citation Impact
- 0.00