Growth of Ultrathick CuInS<sub>2</sub> Shells for Supersized Core/Shell Nanoparticles

The growth of ultrathick shells on quantum dots (QDs) has been demonstrated to provide new aspects of nanoparticles (NPs). Spherical dot-shaped CuInSe<sub>2</sub> QDs were produced with the advantage of shell growth due to their homogeneous surface. The superthickness (∼45 nm) of CuInS<sub>2</sub> was deposited on the CuInSe<sub>2</sub> dots to form supersized CuInSe<sub>2</sub>/CuInS<sub>2</sub> core/shell nanostructures with a tetrakaidecahedron shape to ∼100 nm. This quasi-epitaxial growth mechanism was extended to form supersized ZnSe/CuInS<sub>2</sub> and CuInS<sub>2</sub>/CuInS<sub>2</sub> core/shell nanostructures, thereby providing an efficient method for supersized nanoparticles based on shell growth. The formation of supersized nanoparticles (20-100 nm) may induce new chemistry and physics for nanomaterials, supplying new aspects in fundamental research and the commercial industry.

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Publication Details

Journal
Inorganic Chemistry
Published
2024-11-25
DOI
https://doi.org/10.1021/acs.inorgchem.4c04153
Citations
1
Primary Topic
Quantum Dots Synthesis And Properties
Type
article
Field-Weighted Citation Impact
0.12
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Growth of Ultrathick CuInS2 Shells for Supersized Core/Shell Nanoparticles

Jiajia Ning, Hanzhuang Zhang, Xuerong Song, Hongbo Zhu et al.
1 citations
Inorganic Chemistry
Quantum Dots Synthesis And Properties
0.12
article

Growth of Ultrathick CuInS2 Shells for Supersized Core/Shell Nanoparticles

Jiajia Ning, Hanzhuang Zhang, Xuerong Song, Hongbo Zhu, Wenyu Ji, Yue Qin
article en
1 citations

Abstract

The growth of ultrathick shells on quantum dots (QDs) has been demonstrated to provide new aspects of nanoparticles (NPs). Spherical dot-shaped CuInSe<sub>2</sub> QDs were produced with the advantage of shell growth due to their homogeneous surface. The superthickness (∼45 nm) of CuInS<sub>2</sub> was deposited on the CuInSe<sub>2</sub> dots to form supersized CuInSe<sub>2</sub>/CuInS<sub>2</sub> core/shell nanostructures with a tetrakaidecahedron shape to ∼100 nm. This quasi-epitaxial growth mechanism was extended to form supersized ZnSe/CuInS<sub>2</sub> and CuInS<sub>2</sub>/CuInS<sub>2</sub> core/shell nanostructures, thereby providing an efficient method for supersized nanoparticles based on shell growth. The formation of supersized nanoparticles (20-100 nm) may induce new chemistry and physics for nanomaterials, supplying new aspects in fundamental research and the commercial industry.

Inorganic ChemistryVol. 63(49)
Jilin University (CN), Chinese Academy of Sciences (CN), Changchun Institute of Optics, Fine Mechanics and Physics (CN)
Openalex Percentile: Top 58%
Quantum Dots Synthesis And Properties
0.12
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