Сoncentration Polarization in Membrane Systems

Concentration polarization (CP) in membrane systems is understood as the phenomenon of the emergence of concentration gradients in a solution near the membrane surface, which is a result of the selective transfer of certain components of the solution through the membrane under the influence of transmembrane driving forces. CP accompanies all types of membrane processes. It affects transfer conditions and reduces the efficiency of separation processes: in most cases, there is a decrease in the overall transfer rate and an increase in energy consumption, as well as a loss of permselectivity. This review examines the general patterns and features of the CP phenomenon in the processes of electrodialysis, reverse osmosis, nanofiltration, ultrafiltration, pervaporation, as well as in membrane sensor systems and fuel cells. The fundamental principles of the CP phenomenon and experimental methods for its study are considered.

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Journal
Мембраны и Мембранные технологии
Published
2024-11-24
DOI
https://doi.org/10.31857/s2218117224030017
Primary Topic
Membrane-based Ion Separation Techniques
Type
article
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article

Сoncentration Polarization in Membrane Systems

Natalia Pismenskaya, Е. А. Grushevenko, M. V. Sharafan, И. Л. Борисов et al.
Мембраны и Мембранные технологии
Membrane-based Ion Separation Techniques
article

Сoncentration Polarization in Membrane Systems

Natalia Pismenskaya, Е. А. Grushevenko, M. V. Sharafan, И. Л. Борисов, В. В. Волков, А. В. Паршина, Ilya I. Ryzhkov, О. В. Бобрешова, P. M. Biesheuvel, V. I. Vasil’eva, P. Apel, Victor Nikonenko, A. B. Yaroslavtsev
article en

Abstract

Concentration polarization (CP) in membrane systems is understood as the phenomenon of the emergence of concentration gradients in a solution near the membrane surface, which is a result of the selective transfer of certain components of the solution through the membrane under the influence of transmembrane driving forces. CP accompanies all types of membrane processes. It affects transfer conditions and reduces the efficiency of separation processes: in most cases, there is a decrease in the overall transfer rate and an increase in energy consumption, as well as a loss of permselectivity. This review examines the general patterns and features of the CP phenomenon in the processes of electrodialysis, reverse osmosis, nanofiltration, ultrafiltration, pervaporation, as well as in membrane sensor systems and fuel cells. The fundamental principles of the CP phenomenon and experimental methods for its study are considered.

Мембраны и Мембранные технологииVol. 14(3)
Kuban State University (RU), Russian Academy of Sciences (RU), Joint Institute for Nuclear Research (RU), Institute of General and Inorganic Chemistry (BG), A.V. Topchiev Institute of Petrochemical Synthesis (RU), Institute of Computational Modeling (RU), Siberian Federal University (RU), Voronezh State University (RU)
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Membrane-based Ion Separation Techniques
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