Boosting supercapacitor performance with high-specific surface area porous carbon derived from sugarcane bagasse

Porous carbon materials with an ultra-large specific surface area were synthesized from sugarcane bagasse using a wet mixing process. Initially, the waste sugarcane bagasse underwent pre‑carbonization at 550 °C, resulting in a carbonized material (PC). This PC was then mixed with the activator KOH and subjected to high-temperature activation to produce the porous carbon material. The morphology and structure of the porous carbon were effectively modified by varying the mass ratio of PC to KOH and the mixing method (dry or wet). The electrochemical performance of the synthesized materials was analyzed, revealing that the material produced with a 1:3 mass ratio of PC to KOH using the wet mixing method (WBC-3) exhibited a well-developed pore structure and a specific surface area of 3549.6 m 2 /g. When employed as an electrode material, WBC-3 demonstrated exceptional performance, achieving a specific capacitance of 370 F/g at a current density of 0.5 A/g. The assembled device attained energy densities of 8.3 Wh/kg in 6 M KOH and 16.4 Wh/kg in 1 M Na 2 SO 4 , respectively. Moreover, it exhibited remarkable cyclic stability, retaining 95.3 % of its initial specific capacitance after 8000 charge-discharge cycles at a current density of 10 A/g. • The porous carbon has a specific surface area of 3549.6 m 2 /g. • The porous carbon electrode exhibits excellent pore structure and electrochemical properties, high specific capacity and good cycling stability.

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Publication Details

Journal
Journal of Energy Storage
Published
2024-11-24
DOI
https://doi.org/10.1016/j.est.2024.114718
Citations
18
Primary Topic
Supercapacitor Materials and Fabrication
Type
article
Field-Weighted Citation Impact
2.12
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article

Boosting supercapacitor performance with high-specific surface area porous carbon derived from sugarcane bagasse

Dong Liu, Lele Zhao, Dekun Xu, Zhongnan Kang
18 citations
Journal of Energy Storage
Supercapacitor Materials and Fabrication
2.12
article

Boosting supercapacitor performance with high-specific surface area porous carbon derived from sugarcane bagasse

Dong Liu, Lele Zhao, Dekun Xu, Zhongnan Kang
article en
18 citations

Abstract

Porous carbon materials with an ultra-large specific surface area were synthesized from sugarcane bagasse using a wet mixing process. Initially, the waste sugarcane bagasse underwent pre‑carbonization at 550 °C, resulting in a carbonized material (PC). This PC was then mixed with the activator KOH and subjected to high-temperature activation to produce the porous carbon material. The morphology and structure of the porous carbon were effectively modified by varying the mass ratio of PC to KOH and the mixing method (dry or wet). The electrochemical performance of the synthesized materials was analyzed, revealing that the material produced with a 1:3 mass ratio of PC to KOH using the wet mixing method (WBC-3) exhibited a well-developed pore structure and a specific surface area of 3549.6 m 2 /g. When employed as an electrode material, WBC-3 demonstrated exceptional performance, achieving a specific capacitance of 370 F/g at a current density of 0.5 A/g. The assembled device attained energy densities of 8.3 Wh/kg in 6 M KOH and 16.4 Wh/kg in 1 M Na 2 SO 4 , respectively. Moreover, it exhibited remarkable cyclic stability, retaining 95.3 % of its initial specific capacitance after 8000 charge-discharge cycles at a current density of 10 A/g. • The porous carbon has a specific surface area of 3549.6 m 2 /g. • The porous carbon electrode exhibits excellent pore structure and electrochemical properties, high specific capacity and good cycling stability.

Journal of Energy StorageVol. 104
Wuhan Institute of Technology (CN)
Openalex Percentile: Top 12%
Supercapacitor Materials and Fabrication
2.12
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