The Molecular Additive N‐Acetyl‐L‐Phenylalanine Delays the Crystallization and Suppresses the Phase Impurity for Achieving Triple‐Cation Perovskite Solar Cells with Efficiency Over 25%

The crystallization process plays an important role in the formation of high-quality perovskite film for achieving efficient perovskite solar cells (PSCs), especially in the formation of mixed-cation perovskite film, as there are normally more phase impurities than in pure CH(NH₂)₂PbI₃ (FAPbI₃) film. Herein, a molecular additive strategy, i.e., introducing non-planar molecule N-acetyl-L-phenylalanine (APO) into the lead iodide (PbI₂) precursor solution, is proposed to modulate crystallization kinetics and inhibit the generation of phase impurities of metastable pretreated perovskite film. The delayed crystallization process promotes a sufficient reaction between organic salts solution and inorganic Pb-I framework, and perovskite phase decomposition is prevented by forming strong hydrogen bonds between ─NH and I, resulting in the formation of uniform film with large-size crystal grains and high-purity crystalline phase. Ultimately, the target PSC devices achieve an impressive power conversion efficiency (PCE) of 25.05%, which is among the highest values of triple-cation (FAMACs) PSCs. Meanwhile, PSC modules with 10.8 cm² obtain a PCE of 20.35%. Furthermore, the unencapsulated PSCs retain 94% of the initial efficiency after 40 days of storage under ambient conditions with 20% RH and also yield superior operational stability under light soaking at maximum power point tracking (MPPT) in nitrogen (N₂) atmosphere.