Visible‐Light‐Mediated C−H Difluoroalkylation of (Hetero)arenes: A New Application of Vibration‐Induced‐Emission Molecule 9,14‐Diphenyl‐dihydrodibenzo[<i>a</i>,<i>c</i>]phenazine
Abstract Herein, we report a vibration‐induced emission molecule, 9,14‐diphenyl‐dihydrodibenzo[ a , c ]phenazines (DPAC), compound‐catalyzed C−H difluoroalkylation of (hetero)arenes under visible light conditions. This method demonstrates the promising potential of vibration‐induced‐emission (VIE) molecules in photocatalysis and facilitates a metal‐free synthetic approach for difluoroalkyl (hetero)arenes with broad substrate scope and functional group tolerance.
Authors
- Yifeng Chen (ORCID: https://orcid.org/0000-0003-3239-6209)
- Chengxi Zhang (ORCID: https://orcid.org/0000-0003-1103-804X)
- Zhiyun Zhang (ORCID: https://orcid.org/0000-0001-7513-9427)
Institutions
- East China University of Science and Technology (CN)
- Chinese Academy of Sciences (CN)
- Shanghai Institute of Organic Chemistry (CN)
- Henan Normal University (CN)
Publication Details
- Journal
- ChemCatChem
- Published
- 2024-11-23
- DOI
- https://doi.org/10.1002/cctc.202401699
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- East China University of Science and Technology
- Project 211
- Fundamental Research Funds for the Central Universities