Using stable oxygen isotope dual‐inlet isotope‐ratio mass spectrometry to elucidate uranium transport and mixed <sup>230</sup>Th/U calcite formation ages at the seminal Devils Hole, Nevada, natural laboratory
The continuously submerged Devils Hole δ<sup>18</sup>O chronology is not explained by orbital forcing. Rather, this chronology represents a regional climate record in the southern Great Basin of sea-surface-temperature (SST) variations off California, variations that preceded the last and penultimate deglaciations by 5000 to approximately 10 000 years. Temporal discrepancies between the continuously submerged Devils Hole chronology and other regional δ<sup>18</sup>O records (e.g., the Leviathan chronology) can be explained by unrecognized cryptic, pernicious uranium mobility, leading to model estimations that may be thousands of years younger than actual ages. Consequently, paleo-moisture availability, water-table, and groundwater recharge models based on these mixed uranium-series ages are too young by as much as 12 000 years. The potential for post-formation uranium addition in subaerial cores and speleothems underscores the need for caution in uranium-series dating, highlighting δ<sup>18</sup>O time-series comparisons as a method for identifying mixed ages.
Authors
- Lauren T. Reid (ORCID: https://orcid.org/0000-0003-3872-9596)
- James A. Jordan (ORCID: https://orcid.org/0000-0002-7419-8465)
- Tyler B. Coplen (ORCID: https://orcid.org/0000-0003-4884-6008)
- Robert R. Seal (ORCID: https://orcid.org/0000-0003-0901-2529)
- Adam C. Mumford (ORCID: https://orcid.org/0000-0002-8082-8910)
Institutions
- United States Geological Survey (US)
Publication Details
- Journal
- Rapid Communications in Mass Spectrometry
- Published
- 2024-11-23
- DOI
- https://doi.org/10.1002/rcm.9926
- Primary Topic
- Geology and Paleoclimatology Research
- Type
- article
- Field-Weighted Citation Impact
- 0.00