Direct Synthesis of Sulfinylated Phenanthrenes via BF<sub>3</sub>-Promoted Annulation of 2-Alkynyl Biaryls with Arylsulfinic Acids

A novel approach to sulfinylated phenanthrenes has been developed by BF<sub>3</sub>-promoted annulation of 2-alkynyl biaryls with arylsulfinic acids. This approach utilizes readily available arylsulfinic acids as a sulfinyl source and affords a variety of sulfinylated phenanthrenes in good to excellent yields under simple and mild reaction conditions.

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Publication Details

Journal
The Journal of Organic Chemistry
Published
2024-11-23
DOI
https://doi.org/10.1021/acs.joc.4c02421
Citations
2
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
Field-Weighted Citation Impact
0.50

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article

Direct Synthesis of Sulfinylated Phenanthrenes via BF3-Promoted Annulation of 2-Alkynyl Biaryls with Arylsulfinic Acids

Hui Gao, Tingting Pu, Tao Miao, Zhen Zhang et al.
2 citations
The Journal of Organic Chemistry
Sulfur-Based Synthesis Techniques
0.50
article

Direct Synthesis of Sulfinylated Phenanthrenes via BF3-Promoted Annulation of 2-Alkynyl Biaryls with Arylsulfinic Acids

Hui Gao, Tingting Pu, Tao Miao, Zhen Zhang, Pei-Long Wang, Yue Han
article en
2 citations

Abstract

A novel approach to sulfinylated phenanthrenes has been developed by BF<sub>3</sub>-promoted annulation of 2-alkynyl biaryls with arylsulfinic acids. This approach utilizes readily available arylsulfinic acids as a sulfinyl source and affords a variety of sulfinylated phenanthrenes in good to excellent yields under simple and mild reaction conditions.

The Journal of Organic ChemistryVol. 89(23)
Huaibei Normal University (CN)
National Natural Science Foundation of China, Natural Science Foundation of Anhui Province
Clean water and sanitation
Openalex Percentile: Top 38%
Sulfur-Based Synthesis Techniques
0.50
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