Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect
We assume that two parallel plates are immersed in a binary fluid mixture lying in the one-phase region near the demixing critical point and that the surface of each plate attracts the mixture components differently via short-range interactions. It is known that the composition inhomogeneity caused by the difference can induce a force exerted on the plate at equilibrium. In the present study, we investigate how a temperature gradient imposed vertically on the plates changes the induced force by calculating the composition profile subject to the Soret effect. Numerically solving the derived differential equation, we show that a temperature gradient within the critical regime can change the force distinctly from its equilibrium value and can make the force direction opposite to the one at equilibrium.
Authors
- Youhei Fujitani (ORCID: https://orcid.org/0000-0001-9081-1322)
Institutions
- Keio University (JP)
Publication Details
- Journal
- The Journal of Chemical Physics
- Published
- 2024-11-22
- DOI
- https://doi.org/10.1063/5.0220373
- Citations
- 2
- Primary Topic
- Field-Flow Fractionation Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.75