Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect

We assume that two parallel plates are immersed in a binary fluid mixture lying in the one-phase region near the demixing critical point and that the surface of each plate attracts the mixture components differently via short-range interactions. It is known that the composition inhomogeneity caused by the difference can induce a force exerted on the plate at equilibrium. In the present study, we investigate how a temperature gradient imposed vertically on the plates changes the induced force by calculating the composition profile subject to the Soret effect. Numerically solving the derived differential equation, we show that a temperature gradient within the critical regime can change the force distinctly from its equilibrium value and can make the force direction opposite to the one at equilibrium.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2024-11-22
DOI
https://doi.org/10.1063/5.0220373
Citations
2
Primary Topic
Field-Flow Fractionation Techniques
Type
article
Field-Weighted Citation Impact
0.75
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article

Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect

Youhei Fujitani
2 citations
The Journal of Chemical Physics
Field-Flow Fractionation Techniques
0.75
article

Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect

Youhei Fujitani
article en
2 citations

Abstract

We assume that two parallel plates are immersed in a binary fluid mixture lying in the one-phase region near the demixing critical point and that the surface of each plate attracts the mixture components differently via short-range interactions. It is known that the composition inhomogeneity caused by the difference can induce a force exerted on the plate at equilibrium. In the present study, we investigate how a temperature gradient imposed vertically on the plates changes the induced force by calculating the composition profile subject to the Soret effect. Numerically solving the derived differential equation, we show that a temperature gradient within the critical regime can change the force distinctly from its equilibrium value and can make the force direction opposite to the one at equilibrium.

The Journal of Chemical PhysicsVol. 161(20)
Keio University (JP)
Openalex Percentile: Top 31%
Field-Flow Fractionation Techniques
0.75
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