Samarium Diiodide/Samarium-Mediated Deoxygenative Hydrosilylation of Ketones
The first deoxygenative hydrosilylation of ketones promoted by samarium diiodide and samarium has been reported. In this approach, secondary alkyl silanes are synthesized from unactivated ketones and chlorosilanes in one step. The carbonyl group of ketones is activated by SmI<sub>2</sub>-mediated single-electron transfer process, which follows a deoxygenative elimination of O=Sm. Broad substrate scope and excellent functional group tolerance has been demonstrated.
Authors
- Ruxing Li
- Yilin Ma (ORCID: https://orcid.org/0000-0001-5999-268X)
- Chengwei Liu (ORCID: https://orcid.org/0000-0003-1297-7188)
- Jianwen Zhang (ORCID: https://orcid.org/0000-0002-7897-4206)
Institutions
- Shanghai University (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2024-11-21
- DOI
- https://doi.org/10.1021/acs.joc.4c02052
- Citations
- 5
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 1.25
Funders
- Shanghai University