Selective Oxidation of Alcohols to Carbonyls under Decatungstate‐Mediated Photoelectrochemical Conditions

The Cover Feature depicts the conversion of benzyl alcohols to the corresponding carbonyl compounds. The protocol, also extended to aliphatic derivatives, leverages the unique properties of the decatungstate anion in the role of photocatalyst. The transformation occurred smoothly under photoelectrochemical conditions, requiring the simultaneous irradiation and electrolysis of the reaction mixture, and delivered the desired products in high chemical yields and faradaic efficiencies. More information can be found in the Research Article by D. Ravelli and co-workers (DOI: 10.1002/chem.202402986). Artwork created by Elena Cassera.

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Journal
Chemistry - A European Journal
Published
2024-11-21
DOI
https://doi.org/10.1002/chem.202486504
Primary Topic
Chemical Synthesis and Reactions
Type
article
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article

Selective Oxidation of Alcohols to Carbonyls under Decatungstate‐Mediated Photoelectrochemical Conditions

Andrea Capucciati, Luca Capaldo, Daniele Merli, Davide Ravelli et al.
Chemistry - A European Journal
Chemical Synthesis and Reactions
article

Selective Oxidation of Alcohols to Carbonyls under Decatungstate‐Mediated Photoelectrochemical Conditions

Andrea Capucciati, Luca Capaldo, Daniele Merli, Davide Ravelli, Elena Cassera, Luca Baraglia
article en

Abstract

The Cover Feature depicts the conversion of benzyl alcohols to the corresponding carbonyl compounds. The protocol, also extended to aliphatic derivatives, leverages the unique properties of the decatungstate anion in the role of photocatalyst. The transformation occurred smoothly under photoelectrochemical conditions, requiring the simultaneous irradiation and electrolysis of the reaction mixture, and delivered the desired products in high chemical yields and faradaic efficiencies. More information can be found in the Research Article by D. Ravelli and co-workers (DOI: 10.1002/chem.202402986). Artwork created by Elena Cassera.

Chemistry - A European JournalVol. 30(65)
University of Parma (IT), University of Pavia (IT)
Openalex Percentile: Top 85%
Chemical Synthesis and Reactions
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