Behavior of chemically powered Janus colloids in lyotropic chromonic liquid crystal

Platinum-coated Janus colloids exhibit self-propelled motion in aqueous solution via the catalytic decomposition of hydrogen peroxide. Here, we report their motion in a uniformly aligned nematic phase of lyotropic chromonic liquid crystal, disodium cromoglycate (DSCG). When active Janus colloids are placed in DSCG, we find that the anisotropy of the liquid crystal imposes a strong sense of direction to their motion; the Janus colloids tend to move parallel to the nematic director. Motion analysis over a range of timescales reveals a crossover from ballistic to anomalous diffusive behavior on timescales below the relaxation time for liquid crystal elastic distortions. Surprisingly we observe that smaller particles roll during ballistic motion, whereas larger particles do not. This result highlights the complexity of phoretically-driven particle motion, especially in an anisotropic fluid environment.

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Publication Details

Journal
Physical review. E
Published
2024-11-21
DOI
https://doi.org/10.1103/physreve.110.054704
Primary Topic
Micro and Nano Robotics
Type
article
Field-Weighted Citation Impact
0.00

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article

Behavior of chemically powered Janus colloids in lyotropic chromonic liquid crystal

Oleg D. Lavrentovich, Linda Susan Hirst, Sambeeta Das, Hend Baza et al.
Physical review. E
Micro and Nano Robotics
article

Behavior of chemically powered Janus colloids in lyotropic chromonic liquid crystal

Oleg D. Lavrentovich, Linda Susan Hirst, Sambeeta Das, Hend Baza, Devika Gireesan Sudha, David P. Rivas
article en

Abstract

Platinum-coated Janus colloids exhibit self-propelled motion in aqueous solution via the catalytic decomposition of hydrogen peroxide. Here, we report their motion in a uniformly aligned nematic phase of lyotropic chromonic liquid crystal, disodium cromoglycate (DSCG). When active Janus colloids are placed in DSCG, we find that the anisotropy of the liquid crystal imposes a strong sense of direction to their motion; the Janus colloids tend to move parallel to the nematic director. Motion analysis over a range of timescales reveals a crossover from ballistic to anomalous diffusive behavior on timescales below the relaxation time for liquid crystal elastic distortions. Surprisingly we observe that smaller particles roll during ballistic motion, whereas larger particles do not. This result highlights the complexity of phoretically-driven particle motion, especially in an anisotropic fluid environment.

Physical review. EVol. 110(5)
Kent State University (US), University of California, Merced (US), University of Delaware (US)
National Science Foundation, National Institutes of Health
Openalex Percentile: Top 87%
Micro and Nano Robotics
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Behavior of chemically powered Janus colloids in lyotropic chromonic liquid crystal — Oleg D. Lavrentovich, Linda Susan Hirst, et al. · Physical review. E (2024) | TGRS Research Map | TGRS