Mechanics‐Photophysics Correlation in Tough, Stretchable and Long‐Lived Room Temperature Phosphorescence Ionogels Deciphered by Dynamic Mechanical Analysis

Abstract The development of tough, stretchable and long‐lived room temperature phosphorescence (RTP) materials holds great significance for manufacturing and processing photoluminescent materials, but limited techniques are available to profile their mechanics‐photophysics correlation. Here we report glassy ionogels, and their mechanical properties and photophysical properties are fused by dynamic mechanical analysis (DMA), functioning like a human brain that perceives a material instantaneously by linking sensory perception and cognition. Depending on two special temperatures presented in DMA curves, T loss (the peak of loss modulus ( E” )) and T g (glass transition temperature), the ionogels can vary from being either tough with persistent phosphorescence, extensible with effective phosphorescence or resilience with inefficient phosphorescence. Leveraging this method, we achieve stretchable and long‐lived RTP ionogels with tensile yield strength of 53 MPa, tensile strain of 497 %, Young's modulus of 782 MPa, toughness of 111.2 MJ/m 3 , and lifetime of 113.05 ms. Our work provides a simple yet powerful method to reveal the mechanics‐photophysics correlation of RTP ionogels, to predict their performance without laborious synthesis and characterization, opening new avenues for applications of RTP materials, including applications in harsh conditions (257 K or 347 K), shape memory and shape reconstruction.