Interchain interactions raised the photo-induced [LS] → [HS*] transition temperature to 78 K in a cyanide-bridged [FeIII2Co<sup>II</sup>] chain
Two structurally related cyanide-bridged {Fe 2 Co}-based chain compounds with different interchain π⋯π stacks exhibited different thermal stabilities of the photo-induced HS* states with thermal relaxation temperatures of 130 and 90 K, respectively.
Authors
- Tao Liu (ORCID: https://orcid.org/0000-0003-2891-603X)
- Wenjing Jiang (ORCID: https://orcid.org/0000-0002-1559-9744)
- Hiroki Oshio (ORCID: https://orcid.org/0000-0002-4682-4705)
- Hai‐Lang Zhu (ORCID: https://orcid.org/0000-0001-8857-871X)
- Chunying Duan (ORCID: https://orcid.org/0000-0003-1638-6633)
- Yin‐Shan Meng (ORCID: https://orcid.org/0000-0001-9963-4596)
- Qiang Liu (ORCID: https://orcid.org/0000-0002-7273-1000)
- Han‐Han Lu (ORCID: https://orcid.org/0000-0002-3399-7762)
Institutions
- Chinese Academy of Sciences (CN)
- Dalian University of Technology (CN)
- Dalian University (CN)
- Fujian Institute of Research on the Structure of Matter (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2024-11-20
- DOI
- https://doi.org/10.1039/d4qi02428a
- Citations
- 1
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.12
Funders
- National Natural Science Foundation of China
- Fundamental Research Funds for the Central Universities