Single parameter aging and density scaling

In a recent paper, Di Lisio et al. [J. Chem. Phys. 159, 064505 (2023)] analyzed a series of temperature down-jumps using the single-parameter aging (SPA) ansatz combined with a specific assumption about density scaling in the out-of-equilibrium system and did not find a good prediction for the largest down-jumps. In this paper, we show that SPA in its original form does work for all their data, including large jumps of ΔT > 20 K. Furthermore, we discuss different approaches to the extension of the density scaling concept to out-of-equilibrium systems.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2024-11-20
DOI
https://doi.org/10.1063/5.0234620
Citations
3
Primary Topic
Material Dynamics and Properties
Type
article
Field-Weighted Citation Impact
0.35

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article

Single parameter aging and density scaling

Kristine Niss, Tina Hecksher
3 citations
The Journal of Chemical Physics
Material Dynamics and Properties
0.35
article

Single parameter aging and density scaling

Kristine Niss, Tina Hecksher
article en
3 citations

Abstract

In a recent paper, Di Lisio et al. [J. Chem. Phys. 159, 064505 (2023)] analyzed a series of temperature down-jumps using the single-parameter aging (SPA) ansatz combined with a specific assumption about density scaling in the out-of-equilibrium system and did not find a good prediction for the largest down-jumps. In this paper, we show that SPA in its original form does work for all their data, including large jumps of ΔT > 20 K. Furthermore, we discuss different approaches to the extension of the density scaling concept to out-of-equilibrium systems.

The Journal of Chemical PhysicsVol. 161(19)
Roskilde University (DK)
Villum Fonden
Openalex Percentile: Top 43%
Material Dynamics and Properties
0.35
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