Cooperative Immobilization of Transition-Metal Clusters into Kagome-Type Metal–Organic Framework for C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> Separation
There has long been a pursuit for a metal-organic framework (MOF)-based adsorbent for various hydrocarbon separations. Herein, we utilized simple trimesic acid and 1,2,4-triazole, together with the heterometallic strategy to produce two quaternary MOFs with a kgm-type structure. The cooperative coordination allows the immobilization of metal clusters into the pore channels, creating an appropriate pore size and high density of open metal sites. The resulting material shows excellent C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> separation performance with good stability.
Authors
- Andy Dinh (ORCID: https://orcid.org/0000-0003-4973-5780)
- Jianhua Yu (ORCID: https://orcid.org/0000-0002-5553-2819)
- Xianhui Bu (ORCID: https://orcid.org/0000-0002-2994-4051)
- Xiang Zhao (ORCID: https://orcid.org/0000-0001-7526-8261)
- Xingxing Zhong
- Xiaoyan Jiang (ORCID: https://orcid.org/0000-0003-2141-5785)
Institutions
- Wuhan University (CN)
- California State University, Long Beach (US)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2024-11-19
- DOI
- https://doi.org/10.1021/acs.inorgchem.4c04343
- Citations
- 3
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.48
Funders
- Wuhan University
- Thousand Young Talents Program of China